Integrating Green Nanotechnology into Higher Education: A Pragmatic Framework for Enhancing Environmental Curricula and Sustainability in Libyan Institutions
DOI:
https://doi.org/10.65405/djbx1r42Keywords:
green nanotechnology; higher education; Libya; sustainability education; green chemistry; plant-mediated synthesis; photocatalysis; inquiry-based learningAbstract
This paper proposes a structured curriculum framework for integrating green nanotechnology into undergraduate science and engineering programs in Libyan higher education institutions. Drawing on the principles of green chemistry and sustainability-oriented pedagogy, the framework addresses a persistent tension in resource-constrained academic laboratories: the need to provide rigorous, hands-on scientific training while reducing reliance on hazardous reagents, energy-intensive procedures, and waste streams that many institutions are not equipped to manage safely (Anastas & Warner, 1998; O’Neil et al., 2021; UNESCO, 2017). The proposed model is organized around a three-phase laboratory sequence: preparation of aqueous plant extracts from locally available species, principally Olea europaea (olive) and Punica granatum (pomegranate); biogenic synthesis of metallic nanoparticles; and application of the resulting materials to the photocatalytic degradation of model organic dye pollutants. Each phase is linked to core undergraduate physical chemistry concepts, including reduction kinetics, surface capping, colloidal stability, and surface plasmon resonance (SPR) (Duan et al., 2015; Iravani, 2011; Nasrollahzadeh et al., 2019). By grounding these concepts in observable laboratory phenomena, the framework supports active, inquiry-based learning rather than passive instruction (Hmelo-Silver et al., 2007; Krajcik & Shin, 2014).
The paper is conceptual and design-based. It does not report experimental outcomes; instead, it offers a theoretically grounded model whose empirical validation is identified as a necessary next step. Its main strengths lie in low cost, alignment with local agricultural and environmental conditions, and the ability to connect scientific training with pressing environmental challenges, including dye-contaminated wastewater and sustainable materials development (Makhalanyane et al., 2020; Singh et al., 2018). The paper situates the proposal within the broader context of higher education reform in Libya and calls for systematic pilot implementation across multiple institutions, with attention to learning outcomes, protocol reproducibility, and waste reduction metrics.
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Alotaibi, N. F., ALqarni, L. S., Alghamdi, S. Q., Al-Ghamdi, S. N., Amna, T., Alzahrani, S. S., Moustafa, S. M., Hasanin, T. H., & Nassar, A. M. (2024). Green synthesis of uncoated and olive leaf extract-coated silver nanoparticles: Sunlight photocatalytic, antiparasitic, and antifungal activities. International Journal of Molecular Sciences, 25(6), 3082. https://doi.org/10.3390/ijms25063082
Anastas, P. T., & Warner, J. C. (1998). Green chemistry: Theory and practice. Oxford University Press.
Armstrong, L. B., Rivas, M. C., Douskey, M. C., & Baranger, A. M. (2018). Teaching students the complexity of green chemistry and assessing growth in attitudes and understanding. Current Opinion in Green and Sustainable Chemistry, 13, 61-67. https://doi.org/10.1016/j.cogsc.2018.06.009
Bergal, A., Matar, G. H., & Andaç, M. (2022). Olive and green tea leaf extracts mediated green synthesis of silver nanoparticles (AgNPs): Comparison investigation on characterizations and antibacterial activity. BioNanoScience, 12(2), 307-321. https://doi.org/10.1007/s12668-022-00958-2
Blonder, R., & Sakhnini, S. (2015). The making of nanotechnology: Exposing high-school students to behind-the-scenes of nanotechnology by inviting them to a nanotechnology conference. Nanotechnology Reviews, 4(1), 103-116. https://doi.org/10.1515/ntrev-2014-0016
Brundiers, K., Barth, M., Cebrián, G., Cohen, M., Diaz, L., Doucette-Remington, S., Dripps, W., Habron, G., Harré, N., Jarchow, M., Losch, K., Michel, J., Mochizuki, Y., Rieckmann, M., Parnell, R., Walker, P., & Zint, M. (2021). Key competencies in sustainability in higher education: Toward an agreed-upon reference framework. Sustainability Science, 16(1), 13-29. https://doi.org/10.1007/s11625-020-00838-2
Çelik, H., & Çelik, N. (2024). Review of studies conducted in nanotechnology education: A meta-synthesis study. Discover Education, 3, 155. https://doi.org/10.1007/s44217-024-00277-6
Duan, H., Wang, D., & Li, Y. (2015). Green chemistry for nanoparticle synthesis. Chemical Society Reviews, 44(16), 5778-5792. https://doi.org/10.1039/C4CS00363B
Eilks, I., & Hofstein, A. (Eds.). (2015). Relevant chemistry education: From theory to practice. Sense Publishers. https://doi.org/10.1007/978-94-6300-175-5
Garner, N., Siol, A., & Eilks, I. (2015). The potential of non-formal laboratory settings for innovating the chemistry curriculum and promoting secondary school level students’ education for sustainability. Sustainability, 7(2), 1798-1818. https://doi.org/10.3390/su7021798
Grieger, K., Hill, B., & Leontyev, A. (2022). Exploring curriculum adoption of green and sustainable chemistry in undergraduate organic chemistry courses: Results from a national survey in the United States. Green Chemistry, 24(22), 8770-8782. https://doi.org/10.1039/D2GC01901G
Hingant, B., & Albe, V. (2010). Nanosciences and nanotechnologies learning and teaching in secondary education: A review of literature. Studies in Science Education, 46(2), 121-152. https://doi.org/10.1080/03057267.2010.504543
Hmelo-Silver, C. E., Duncan, R. G., & Chinn, C. A. (2007). Scaffolding and achievement in problem-based and inquiry learning: A response to Kirschner, Sweller, and Clark (2006). Educational Psychologist, 42(2), 99-107. https://doi.org/10.1080/00461520701263368
Iravani, S. (2011). Green synthesis of metal nanoparticles using plants. Green Chemistry, 13(10), 2638-2650. https://doi.org/10.1039/C1GC15386B
Jadoun, S., Arif, R., Jangid, N. K., & Meena, R. K. (2021). Green synthesis of nanoparticles using plant extracts: A review. Environmental Chemistry Letters, 19(1), 355-374. https://doi.org/10.1007/s10311-020-01074-x
Joshi, S. J., Geetha, S. J., Al-Mamari, S., & Al-Azkawi, A. (2018). Green synthesis of silver nanoparticles using pomegranate peel extracts and its application in photocatalytic degradation of methylene blue. Jundishapur Journal of Natural Pharmaceutical Products, 13(1), e67846. https://doi.org/10.5812/jjnpp.67846
Kharissova, O. V., Kharisov, B. I., Méndez, U. O., & López, I. (2019). The trends of green nanotechnology: From materials to education. Critical Reviews in Solid State and Materials Sciences, 44(3), 161-182. https://doi.org/10.1080/10408436.2018.1443248
Krajcik, J. S., & Shin, N. (2014). Project-based learning. In R. K. Sawyer (Ed.), The Cambridge handbook of the learning sciences (2nd ed., pp. 275-297). Cambridge University Press.
Laherto, A. (2020). Incorporating nanoscience and nanotechnology into secondary and post-secondary science education: A review of current practice and perspectives. NanoEthics, 14(1), 1-14. https://doi.org/10.1007/s11569-019-00361-6
Leal Filho, W., Raath, S., Lazzarini, B., Vargas, V. R., de Souza, L., Anholon, R., Quelhas, O. L. G., Haddad, R., Klavins, M., & Orlovic, V. L. (2018). The role of transformation in learning and education for sustainability. Journal of Cleaner Production, 199, 286-295. https://doi.org/10.1016/j.jclepro.2018.07.017
Mack, J., Shultz, M. M., Decker, C., & Wilkes, M. A. (2008). Less is more: A sustainable approach to the practice of introductory organic laboratory. Green Chemistry Letters and Reviews, 1(3-4), 175-181. https://doi.org/10.1080/17518250802394516
Makhalanyane, T. P., Valverde, A., Gunnigle, E., Frossard, A., Snape, J. R., & Cowan, D. A. (2020). Green nanotechnology applications in environmental sustainability. Journal of Cleaner Production, 254, 120036. https://doi.org/10.1016/j.jclepro.2020.120036
Mustapha, T., Misni, N., Ithnin, N. R., Daskum, A. M., & Unyah, N. Z. (2022). A review on plants and microorganisms mediated synthesis of silver nanoparticles, role of plant metabolites and applications. International Journal of Environmental Research and Public Health, 19(2), 674. https://doi.org/10.3390/ijerph19020674
Nasrollahzadeh, M., Sajadi, S. M., Sajjadi, M., & Issaabadi, Z. (2019). An introduction to green nanotechnology. In Interface Science and Technology (Vol. 28, pp. 1-27). Academic Press. https://doi.org/10.1016/B978-0-12-813586-0.00001-X
O’Neil, N. J., Scott, S., Relph, R., & Ponnusamy, E. (2021). Approaches to incorporating green chemistry and safety into laboratory culture. Journal of Chemical Education, 98(1), 84-91. https://doi.org/10.1021/acs.jchemed.0c00134
Rieckmann, M. (2018). Learning to transform the world: Key competencies in ESD. In A. Leicht, J. Heiss, & W. J. Byun (Eds.), Issues and trends in education for sustainable development (pp. 39-59). UNESCO. https://unesdoc.unesco.org/ark:/48223/pf0000261445.
algasim Alrrjipi, J. A. (2026). Silent Data Waste in Public Laboratories: A Conceptual Framework for Sustainable Data Driven Management. Al-Farooq Journal of Sciences, 2(2), 36-48.
Shahzadi, S., Fatima, S., ul ain, Q., Shafiq, Z., & Janjua, M. R. S. A. (2025). A review on green synthesis of silver nanoparticles (SNPs) using plant extracts: A multifaceted approach in photocatalysis, environmental remediation, and biomedicine. RSC Advances, 15, 4978-4999. https://doi.org/10.1039/d4ra07519f.
Alboueishi, F. A. A. (2026). Efficacy of Curcumin on Inflammatory Biomarkers in Type 2 Diabetes: A Meta-Analysis of Clinical Trials and Animal Studies Systematic Review & Meta-Analysis (PRISMA 2020) Field: Botany & Complementary Medicine. Al-Farooq Journal of Sciences, 2(2), 15-35.
Shankar, S. S., Rai, A., Ahmad, A., & Sastry, M. (2004). Rapid synthesis of Au, Ag, and bimetallic Au core-Ag shell nanoparticles using Neem (Azadirachta indica) leaf broth. Journal of Colloid and Interface Science, 275(2), 496-502. https://doi.org/10.1016/j.jcis.2004.03.003
Sinakou, E., Boeve-de Pauw, J., Goossens, M., & Van Petegem, P. (2018). Academics in the field of education for sustainable development: Their conceptions of sustainable development. Journal of Cleaner Production, 184, 321-332. https://doi.org/10.1016/j.jclepro.2018.02.279
Singh, J., Dutta, T., Kim, K. H., Rawat, M., Samddar, P., & Kumar, P. (2018). ‘Green’ synthesis of metals and their oxide nanoparticles: Applications for environmental remediation. Journal of Nanobiotechnology, 16, 84. https://doi.org/10.1186/s12951-018-0408-4
Sweeney, A. E., Seal, S., & Vaidya, S. (2006). The promise and peril of nanotechnology education. Science and Engineering Ethics, 12(3), 569-584. https://doi.org/10.1007/s11948-006-0051-9
Timmer, B. J. J., Schaufelberger, F., Hammarberg, D., Franzén, J., Ramström, O., & Dinér, P. (2018). Simple and effective integration of green chemistry and sustainability education into an existing organic chemistry course. Journal of Chemical Education, 95(8), 1301-1306. https://doi.org/10.1021/acs.jchemed.7b00720
UNESCO. (2017). Education for sustainable development goals: Learning objectives. United Nations Educational, Scientific and Cultural Organization. https://unesdoc.unesco.org/ark:/48223/pf0000247444
Vanlalveni, C., Lallianrawna, S., Biswas, A., Selvaraj, M., Changmai, B., & Rokhum, S. L. (2021). Green synthesis of silver nanoparticles using plant extracts and their antimicrobial activities: A review of recent literature. RSC Advances, 11(5), 2804-2837. https://doi.org/10.1039/D0RA09941D.
Elshakh, A. S., Al Mabruk, S., Buijlayyil, M., Al Mansouri, E. N., Elsheikh, Z. S., Elyasir, E. N., ... & Azzouz, F. M. (2026). Ecological Assessment and Local Knowledge of the Invasive Lionfish (Pterois miles) in the Coastal Waters of Derna, Eastern Libya. Al-Farooq Journal of Sciences, 2(2), 1-14.
Wiek, A., Withycombe, L., & Redman, C. L. (2011). Key competencies in sustainability: A reference framework for academic program development. Sustainability Science, 6(2), 203-218. https://doi.org/10.1007/s11625-011-0132-6.
Azouz, A., Fawzi, M., Mohammed, I., Hamed, O., Maher, A., & Baddi, M. (2026). Influence of Electrolyte Chemistry and Electrode Material on Hydrogen Production Performance in Alkaline Water Electrolysis. Al-Farooq Journal of Sciences, 2(2), 49-66.
Zhang, M., Day, E. L., McFall-Boegeman, H., Petritis, S. J., & Cooper, M. M. (2023). Incorporation of green chemistry into undergraduate organic laboratory using cooperative project-based experiments and case studies. Green Chemistry Letters and Reviews, 16(1), 2183781. https://doi.org/10.1080/17518253.2023.2183781










